A new supramolecular organic-inorganic adduct: {[Eu(CH(3)OH)(H(2)O)(8)](2) [Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)).2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O)

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Título:	A new supramolecular organic-inorganic adduct: {[Eu(CH(3)OH)(H(2)O)(8)](2) [Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)).2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O)
Autor:	Soares-Santos, Paula C. R. Cunha-Silva, Luís Sousa, Filipa L. Sousa, Joana L. C. Gates, Paul J. Klinowski, Jacek Trindade, Tito Rocha, João Cavaleiro, Ana M. V. Almeida Paz, Filipe A. Nogueira, Helena I. S.
Palavras-chave:	Organic–inorganic hybrid crystalline compounds Polyoxometalate Crown ether Europium
Data:	22-Mar-2011
Editora:	Elsevier
Resumo:	A new europium(III) supramolecular adduct constructed from alpha-Keggin-type [PW(12)O(40)](3-) anions, benzo-15-crown-5 and dibenzo-30-crown-10 molecules, {[Eu(CH(3)OH)(H(2)O)(8)](2)[Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)). 2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O), was prepared and its crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using FT-IR, FT-Raman and (13)C CP MAS NMR spectroscopy. (c) 2011 Elsevier B.V. All rights reserved.
Peer review:	yes
URI:	http://hdl.handle.net/10773/6252
DOI:	10.1016/j.molstruc.2011.01.007
ISSN:	0022-2860
Aparece nas coleções:	CICECO - Artigos DQ - Artigos

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Journal of Molecular Structure 989 (2011) 80–85.pdf	Main article	1.33 MB	Adobe PDF