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Title: New porphyrin derivatives for phosphate anion sensing in both organic and aqueous media
Author: Rodrigues, João M. M.
Farinha, Andreia S. F.
Muteto, Paulino V.
Woranovicz-Barreira, Sandra M.
Almeida Paz, Filipe A.
Neves, Maria G. P. M. S.
Cavaleiro, José A. S.
Tomé, Augusto C.
Gomes, M. Teresa S. R.
Sessler, Jonathan L.
Tomé, João P. C.
Keywords: BINDING
Issue Date: 2014
Publisher: Royal Society of Chemistry
Abstract: New porphyrin-based anion receptors have been prepared from meso-tetrakis(pentafluorophenyl) porphyrin (TPPF20) and diamine derivatives. These receptors (compounds 1-3) interact preferentially with phosphate anions both in organic solutions and in basic aqueous media when coated on gold piezoelectric quartz crystals. A single crystal X-ray structure of the bis-HF complex of a imine derivative of 1 was obtained; it serves to highlight the main interactions between the anion and cation receptors in the solid state.
Peer review: yes
DOI: 10.1039/c3cc47504b
ISSN: 1359-7345
Appears in Collections:CESAM - Artigos
CICECO - Artigos
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