Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10773/19314
Título: | Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII) |
Autor: | Bruno, Sofia M. Pillinger, Martyn Kuehn, Fritz E. Goncalves, Isabel S. Valente, Anabela A. |
Palavras-chave: | LEWIS ACIDITY CAMPHOLENIC ALDEHYDE VERSATILE CATALYST MTO REARRANGEMENT SILICA EPOXIDATION CHEMISTRY CHEMICALS EPOXIDES |
Data: | 2013 |
Editora: | ELSEVIER SCIENCE BV |
Resumo: | The catalytic performance of methyltrioxorhenium(VII) (MTO) has been investigated for the first time in the isomerization of a-pinene oxide (PinOx) into campholenic aldehyde (CPA). The high isomerization activity of MTO is coupled with high selectivity to CPA: CPA yield of up to 87% (100% conversion) was obtained by using alpha,alpha,alpha-trifluorotoluene as solvent at 15 degrees C. Catalyst recycling is possible in a relatively simple fashion by using MTO coupled to an appropriate ionic liquid. The catalytic application of MTO in the isomerization of PinOx versus the integrated epoxidation-isomerization process of the conversion of alpha-pinene into CPA is discussed. (C) 2013 Elsevier B.V. All rights reserved. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19314 |
DOI: | 10.1016/j.catcom.2013.02.001 |
ISSN: | 1566-7367 |
Versão do Editor: | 10.1016/j.catcom.2013.02.001 |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Isomerization of α-pinene oxide in the presence of methyltrioxorhenium(VII)_10.1016j.catcom.2013.02.001.pdf | 309.91 kB | Adobe PDF |
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