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Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/19314
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dc.contributor.authorBruno, Sofia M.pt
dc.contributor.authorPillinger, Martynpt
dc.contributor.authorKuehn, Fritz E.pt
dc.contributor.authorGoncalves, Isabel S.pt
dc.contributor.authorValente, Anabela A.pt
dc.date.accessioned2017-12-07T19:08:27Z-
dc.date.issued2013pt
dc.identifier.issn1566-7367pt
dc.identifier.urihttp://hdl.handle.net/10773/19314-
dc.description.abstractThe catalytic performance of methyltrioxorhenium(VII) (MTO) has been investigated for the first time in the isomerization of a-pinene oxide (PinOx) into campholenic aldehyde (CPA). The high isomerization activity of MTO is coupled with high selectivity to CPA: CPA yield of up to 87% (100% conversion) was obtained by using alpha,alpha,alpha-trifluorotoluene as solvent at 15 degrees C. Catalyst recycling is possible in a relatively simple fashion by using MTO coupled to an appropriate ionic liquid. The catalytic application of MTO in the isomerization of PinOx versus the integrated epoxidation-isomerization process of the conversion of alpha-pinene into CPA is discussed. (C) 2013 Elsevier B.V. All rights reserved.pt
dc.language.isoengpt
dc.publisherELSEVIER SCIENCE BVpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F46473%2F2008/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/COMPETE/132936/PTpt
dc.rightsrestrictedAccesspor
dc.subjectLEWIS ACIDITYpt
dc.subjectCAMPHOLENIC ALDEHYDEpt
dc.subjectVERSATILE CATALYSTpt
dc.subjectMTOpt
dc.subjectREARRANGEMENTpt
dc.subjectSILICApt
dc.subjectEPOXIDATIONpt
dc.subjectCHEMISTRYpt
dc.subjectCHEMICALSpt
dc.subjectEPOXIDESpt
dc.titleIsomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)pt
dc.typearticlept
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage40pt
degois.publication.lastPage44pt
degois.publication.titleCATALYSIS COMMUNICATIONSpt
degois.publication.volume35pt
dc.date.embargo10000-01-01-
dc.relation.publisherversion10.1016/j.catcom.2013.02.001pt
dc.identifier.doi10.1016/j.catcom.2013.02.001pt
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