Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/6252
Title: A new supramolecular organic-inorganic adduct: {[Eu(CH(3)OH)(H(2)O)(8)](2) [Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)).2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O)
Author: Soares-Santos, Paula C. R.
Cunha-Silva, Luís
Sousa, Filipa L.
Sousa, Joana L. C.
Gates, Paul J.
Klinowski, Jacek
Trindade, Tito
Rocha, João
Cavaleiro, Ana M. V.
Paz, Filipe A. Almeida
Nogueira, Helena I. S.
Keywords: Organic–inorganic hybrid crystalline compounds
Polyoxometalate
Crown ether
Europium
Issue Date: 22-Mar-2011
Publisher: Elsevier
Abstract: A new europium(III) supramolecular adduct constructed from alpha-Keggin-type [PW(12)O(40)](3-) anions, benzo-15-crown-5 and dibenzo-30-crown-10 molecules, {[Eu(CH(3)OH)(H(2)O)(8)](2)[Eu(H(2)O)(8)][PW(12)O(40)](3)}.8(C(14)H(20)O(5)). 2(C(28)H(40)O(10)).6(CH(3)OH).6(H(2)O), was prepared and its crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using FT-IR, FT-Raman and (13)C CP MAS NMR spectroscopy. (c) 2011 Elsevier B.V. All rights reserved.
Peer review: yes
URI: http://hdl.handle.net/10773/6252
DOI: 10.1016/j.molstruc.2011.01.007
ISSN: 0022-2860
Appears in Collections:DQ - Artigos

Files in This Item:
File Description SizeFormat 
Journal of Molecular Structure 989 (2011) 80–85.pdfMain article1.33 MBAdobe PDFrestrictedAccess


FacebookTwitterLinkedIn
Formato BibTex MendeleyEndnote Degois 

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.