Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/5231
Title: | Synthesis of flavonoid-type compounds from methyl dehydroabietates |
Author: | Monteiro, Silvia M. C. S. Silvestre, Armando J. D. Silva, Artur M. S. Cavaleiro, José A. S. |
Keywords: | Chromones Chalcones Dehydroabietate derivatives NMR MS |
Issue Date: | 2008 |
Publisher: | Springer Verlag |
Abstract: | The synthesis of new flavone-type compounds bearing several chiral centres, 12- and 14-(2'-chromonyl)dehydroabietates, are reported. This synthesis started from the aldol condensation of methyl 12- and 14-formyldehydroabietates with 2'-hydroxyacetophenones in order to prepare the corresponding chalcone-type compounds, which were then transformed in the expected flavone-type compounds by cyclodehydrogenation with DMSO and a catalytic amount of iodine. All compounds were exhaustively characterised by NMR and MS techniques. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/5231 |
ISSN: | 0026-9247 |
Appears in Collections: | DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Monatsh Chem 2008.pdf | 183.08 kB | Adobe PDF |
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