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http://hdl.handle.net/10773/35273
Título: | Chemically expanded graphite-based ultra-high molecular weight polyethylene nanocomposites with enhanced mechanical properties |
Autor: | Somberg, Julian Gonçalves, Gil Soria Sanchez, Maria Emami, Nazanin |
Palavras-chave: | Chemically expanded graphite UHMWPE Dynamic mechanical analysis Hydrophobicity Wear |
Data: | 2022 |
Editora: | Elsevier |
Resumo: | Chemically expanded graphite (CEG) has recently been identified as promising reinforcement for polymer composites with the ability for commercial up-scaling. In this work, silane and polydopamine functionalized CEG were successfully synthesized and employed to prepare ultra-high molecular weight polyethylene (UHMWPE) composites with an enhanced interfa- cial compatibility. Characterisation of the functionalized CEG indicated a significant oxygen reduction, which gave rise to a restoration of the graphitic structure. The polydopamine functionalized CEG showed an enhanced exfoliation and dispersion in organic solvents and the polymer matrix with respect to the non-modified CEG. The silane functionalized CEG provided a higher affinity towards the matrix with polymer chains covering the CEG sheets on the fracture surfaces. The addition of functionalized CEG enhanced the mechanical prop- erties of the matrix with an increase in micro-hardness of up to 25% and storage modulus up to 58%. Furthermore, the hydrophobicity of the composites was significantly enhanced with an increase in water contact angle from 98.6◦ for the pure polymer to 119◦ for 5 wt% silane functionalized CEG. Preliminary wear experiments indicated the potential of the composites for tribological applications with a decrease in wear rate of up to 99% under water lubricated conditions. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/35273 |
DOI: | 10.1016/j.matdes.2022.111304 |
ISSN: | 0261-3069 |
Aparece nas coleções: | TEMA - Artigos |
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