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http://hdl.handle.net/10773/20840| Title: | Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate |
| Author: | Duarte, Tiago A. G. Santos, Isabel C. M. S. Simoes, Mario M. Q. Neves, M. Graca P. M. S. Cavaleiro, Ana M. V. Cavaleiro, Jose A. S. |
| Keywords: | KEGGIN-TYPE POLYOXOMOLYBDATES SELECTIVE OXIDATION MOLECULAR-OXYGEN BIFUNCTIONAL CATALYSTS POLYOXOTUNGSTATES MONOTERPENES EPOXIDATION CHEMISTRY ALCOHOLS ALKENES |
| Issue Date: | 2014 |
| Publisher: | SPRINGER |
| Abstract: | [PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20840 |
| DOI: | 10.1007/s10562-013-1101-8 |
| ISSN: | 1011-372X |
| Publisher Version: | 10.1007/s10562-013-1101-8 |
| Appears in Collections: | CICECO - Artigos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Homogeneous catalytic oxidation of olefins with hydrogen peroxide in the presence of a manganese-substituted polyoxomolybdate_10.1007s10562-013-1101-8.pdf | 1.05 MB | Adobe PDF |  |
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