Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20840
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Duarte, Tiago A. G. | pt |
dc.contributor.author | Santos, Isabel C. M. S. | pt |
dc.contributor.author | Simoes, Mario M. Q. | pt |
dc.contributor.author | Neves, M. Graca P. M. S. | pt |
dc.contributor.author | Cavaleiro, Ana M. V. | pt |
dc.contributor.author | Cavaleiro, Jose A. S. | pt |
dc.date.accessioned | 2017-12-07T20:01:17Z | - |
dc.date.issued | 2014 | pt |
dc.identifier.issn | 1011-372X | pt |
dc.identifier.uri | http://hdl.handle.net/10773/20840 | - |
dc.description.abstract | [PMo11Mn(H2O)O-39](5-) is used as catalyst in the homogeneous oxidation of cis-cyclooctene, cyclohexene, styrene, and geraniol with H2O2 in acetonitrile. Oxidation of cis-cyclooctene gives only cyclooctene oxide; cyclohexene-1,2-diol is the main product for cyclohexene; styrene is preferentially oxidized to benzaldehyde; a TOF almost as high as 28800 h(-1) is reached for geraniol oxidation. | pt |
dc.language.iso | eng | pt |
dc.publisher | SPRINGER | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | KEGGIN-TYPE POLYOXOMOLYBDATES | pt |
dc.subject | SELECTIVE OXIDATION | pt |
dc.subject | MOLECULAR-OXYGEN | pt |
dc.subject | BIFUNCTIONAL CATALYSTS | pt |
dc.subject | POLYOXOTUNGSTATES | pt |
dc.subject | MONOTERPENES | pt |
dc.subject | EPOXIDATION | pt |
dc.subject | CHEMISTRY | pt |
dc.subject | ALCOHOLS | pt |
dc.subject | ALKENES | pt |
dc.title | Homogeneous Catalytic Oxidation of Olefins with Hydrogen Peroxide in the Presence of a Manganese-Substituted Polyoxomolybdate | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 104 | pt |
degois.publication.issue | 1 | pt |
degois.publication.lastPage | 111 | pt |
degois.publication.title | CATALYSIS LETTERS | pt |
degois.publication.volume | 144 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1007/s10562-013-1101-8 | pt |
dc.identifier.doi | 10.1007/s10562-013-1101-8 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Homogeneous catalytic oxidation of olefins with hydrogen peroxide in the presence of a manganese-substituted polyoxomolybdate_10.1007s10562-013-1101-8.pdf | 1.05 MB | Adobe PDF |
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