Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10773/20435
Título: | Synthesis of cobalt aluminate nanopigments by a non-aqueous sol-gel route |
Autor: | Karmaoui, Mohamed Silva, Nuno J. O. Amaral, Vitor S. Ibarra, Alfonso Millan, Angel Palacio, Fernando |
Palavras-chave: | SUPERCRITICAL WATER MEDIATED SYNTHESIS PIGMENT PARTICLES COAL2O4 SPINELS NANOCRYSTALS ORDER |
Data: | 2013 |
Editora: | ROYAL SOC CHEMISTRY |
Resumo: | Here we report the chemical synthesis of cobalt aluminum oxide (CoAl2O4) nanoparticles by a non-aqueous sol-gel route. The one-pot procedure is carried out at mild temperatures (in the 150 to 300 degrees C range), and consists of the reaction between cobalt acetate and aluminium isopropoxide in benzyl alcohol. The resulting CoAl2O4 nanoparticles show an unusually low average size, between 2.5 and 6.2 nm, which can be controlled by the synthesis temperature. The colorimetric properties of the nanoparticles are also determined by the synthesis temperature and the characteristic blue color of CoAl2O4 pigments is achieved in samples prepared at T >= 200 degrees C. The nanoparticles are antiferromagnetically ordered below similar to 27 K with an uncompensated configuration. The uncompensated moment shows the typical features of strongly interacting superparamagnetic nanoparticles and spin-glass systems. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20435 |
DOI: | 10.1039/c3nr34229h |
ISSN: | 2040-3364 |
Versão do Editor: | 10.1039/c3nr34229h |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Synthesis of cobalt aluminate nanopigments by a non-aqueous sol-gel route_10.1039c3nr34229h.pdf | 1.04 MB | Adobe PDF |
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