Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10773/20326
Título: | On the Formation of a Third, Nanostructured Domain in Ionic Liquids |
Autor: | Pereiro, Ana B. Pastoriza-Gallego, M. J. Shimizu, Karina Marrucho, Isabel M. Canongia Lopes, Jose N. Pineiro, Manuel M. Rebelo, Luis Paulo N. |
Palavras-chave: | MOLECULAR-FORCE FIELD ANIONS SEGREGATION BROMIDE SOLUTES CATIONS |
Data: | 2013 |
Editora: | AMER CHEMICAL SOC |
Resumo: | The study of solid-fluid transitions in fluorinated ionic liquids using differential scanning calorimetry, rheology, and molecular modeling techniques is an essential step toward the understanding of their dynamics and the thermodynamics and the development of potential applications. Two fluorinated ionic liquids were studied: 1-hexyl- 3-methylimidazolium perfluorobutanesulfonate, HMIm(PFBu)SO3, and tetrabutylammonium perfluorobutanesulfonate, NB4(PFBu)SO3. The experimental calorimetric and rheological data were analyzed taking into account the possible mesoscale structure of the two fluorinated ionic liquids. The simulation results indicate the possible formation of three nanosegregated domains-polar, nonpolar, and fluorous-that may have a profound impact on ionic liquid research. In the case of HMIm (PFBu)SO3 the three types of mesoscopic domains can act as interchangeable jigsaw pieces enabling the formation of multiple types of crystals and inducing the observed calorimetry and rheological trends. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20326 |
DOI: | 10.1021/jp402300c |
ISSN: | 1520-6106 |
Versão do Editor: | 10.1021/jp402300c |
Aparece nas coleções: | CICECO - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
On the Formation of a Third Nanostructured Domain in Ionic Liquids_10.1021jp402300c.pdf | 2.52 MB | Adobe PDF |
Todos os registos no repositório estão protegidos por leis de copyright, com todos os direitos reservados.