Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/5528
Title: | Optimization of phenolic compounds analysis by capillary electrophoresis |
Author: | Lima, Diana L D Duarte, Armando C Esteves, Valdemar I |
Keywords: | Capillary zone electrophoresis Humic acids Phenols CuO oxidation |
Issue Date: | 2007 |
Publisher: | Elsevier |
Abstract: | Operational parameters like migration time, temperature, voltage, composition of background electrolyte and content of organic modifier were optimized in CZE for the determination of lignin-like phenolic compounds. The applied background electrolyte buffer consisted of a Na2B4O7, KH2PO4 aqueous solution, pH 9.15 using acetonitrile as organic modifier with UV-detection. Compounds, such as acetosyringone, acetovanillone, syringealdehyde, p-hydroxyacetophenone, vanillin, syringic acid, ferulic acid, p-hydroxybenzaldehyde, p-coumaric acid, vanillic acid and p-hydroxybenzoic acid were applied as reference compounds. The quality and quantity of different phenolic compounds obtained upon alkaline CuO oxidation of a commercial humic acid were determined with CZE using ethylvanillin as internal standard. The optimized CZE revealed has being an appropriate method since it is quick, sensitive and quantitative and does not require a time-consuming sample preparation. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/5528 |
DOI: | 10.1016/j.talanta.2007.01.049 |
ISSN: | 0039-9140 |
Appears in Collections: | DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
TAL8975_phenols_EC_2007.pdf | 279.04 kB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.