Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/21032
Title: | CO2 and N-2 Adsorption in Nano-porous BEA Type Zeolite with Different Cations |
Author: | Pillai, Renjith S. Titus, Elby |
Keywords: | CANONICAL MONTE-CARLO GAS PERMEATION PROPERTIES VOLUMETRIC MEASUREMENTS CARBON-DIOXIDE EQUILIBRIUM ADSORPTION MOLECULAR SIMULATIONS SEPARATION PROPERTIES DYNAMICS SIMULATIONS FAUJASITE SYSTEMS SORPTION |
Issue Date: | 2015 |
Publisher: | ELSEVIER SCIENCE BV |
Abstract: | Adsorption of CO2 and N-2 in nano-porous BEA having SiO2/Al2O3 of 25, BEA(25), was studied by combining equilibrium adsorption measurements and Grand Canonical Monte Carlo (GCMC) simulation. CO2 sorption is observed to show higher sorption capacity than N-2 in all cation exchanged zeolite samples. On exchanging the BEA(25) with various cations, Li+, K+, Cs+, Ca2+, Sr2+, and Ba2+, the adsorption capacity of CO2 and N-2 are increased in these type of zeolites. The isosteric heat of sorption data shows stronger interactions of both CO2 and N-2 molecules in BEA(25) on decreasing size of the extra-framework cation. Simulation of the CO2 and N-2 sorption in cation exchanged BEA(25) clearly shows that the adsorbed CO2 and N-2 molecules sit closely to the extra-framework cations accessible through the large cage. Simulation of adsorption isotherms and heats of adsorption of CO2 and N-2 in cation exchanged BEA(25) match reasonably well with the experimental results. (C) 2015 Elsevier Ltd. All rights reserved. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/21032 |
DOI: | 10.1016/j.matpr.2015.04.054 |
ISSN: | 2214-7853 |
Publisher Version: | 10.1016/j.matpr.2015.04.054 |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
CO2 and N2 Adsorption in Nano-porous BEA Type Zeolite with Different Cations_10.1016j.matpr.2015.04.054.pdf | 1.26 MB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.