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http://hdl.handle.net/10773/20387| Title: | Catalytic dehydration of fructose to HMF over sulfonic acid functionalized periodic mesoporous organosilicas: role of the acid density |
| Author: | Bispo, Claudia Vigier, Karine De Oliveira Sardo, Mariana Bion, Nicolas Mafra, Luis Ferreira, Paula Jerome, Francois |
| Keywords: | CHEMISORBED TRIETHYLPHOSPHINE OXIDE P-31 MAS-NMR IONIC LIQUIDS SILICA SBA-15 WATER EFFICIENT WALLS |
| Issue Date: | 2014 |
| Publisher: | ROYAL SOC CHEMISTRY |
| Abstract: | Here, we reported the catalytic efficiency of sulfonic acid functionalized periodic mesoporous organosilica (PMO) materials with crystal-like pore walls in the dehydration of fructose to HMF in water. We found that the proton loading, the localization of acid sites and the surface hydrophobicity played a crucial role in the PMO activity. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20387 |
| DOI: | 10.1039/c4cy00137k |
| ISSN: | 2044-4753 |
| Publisher Version: | 10.1039/c4cy00137k |
| Appears in Collections: | CICECO - Artigos |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Catalytic dehydration of fructose to HMF over sulfonic acid functionalized periodic mesoporous organosilicas role of the acid density_10.1039c4cy00137k.pdf | 379.52 kB | Adobe PDF |  |
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