Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/19736
Title: | Reversible click chemistry at the service of macromolecular materials. Part 4: Diels-Alder non-linear polycondensations involving polyfunctional furan and maleimide monomers |
Author: | Gandini, Alessandro Silvestre, Armando Coelho, Dora |
Keywords: | POLY(STYRENE-CO-FURFURYL METHACRYLATE) POLYMERIC MATERIALS CROSS-LINKING BISMALEIMIDE POLYSTYRENE MOIETIES ADDUCTS STYRENE |
Issue Date: | 2013 |
Publisher: | ROYAL SOC CHEMISTRY |
Abstract: | The polymerisation of furan monomers and the exploitation of some of the chemical peculiarities of the furan heterocycle have generated a wide diversity of macromolecular materials based on renewable resources. In particular, the application of the DA cycloaddition to the macromolecular chemistry opened new ways to synthesize materials with unique properties, such as self-mendability and network recyclability. In this study, non-linear polycondensations between di- and tri-functional furan (A(n)) and maleimide (B-m) monomers by means of the DA reaction are presented. The use of complementary monomers bearing more than two functionalities led to highly crosslinked structures under appropriate stoichiometric conditions, and thus, can be applied in the preparation of \"mendable\" materials. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19736 |
DOI: | 10.1039/c2py20805a |
ISSN: | 1759-9954 |
Publisher Version: | 10.1039/c2py20805a |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.