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Title: | Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]manganese(II) bis(hexafluorido-phosphate) |
Author: | Lourenço, Leandro M. O. Almeida Paz, Filipe A. Fernandes, José A. |
Keywords: | Crystal structure Metalloligand Manganese Terpyridine |
Issue Date: | 2015 |
Publisher: | International Union of Crystallography |
Abstract: | The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]mangan-ese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)2](PF6)2·-H2O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]manganese(II) bis-(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)2]-(PF6)2·CH3COCH3, are described. At 150 K, (1) and (2) have monoclinic (P21/c) and orthorhombic (C2221) symmetries, respectively. Both structures exhibit octahedrally coordinated MnII atoms and disorder. They display weak interactions, such as C - H⋯F, C - H⋯N, C - H⋯π, F⋯π and π-π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/18219 |
DOI: | 10.1107/S2056989015003503 |
ISSN: | 2056-9890 |
Appears in Collections: | CICECO - Artigos DQ - Artigos |
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Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-22′6′2″-terpyridine]manganese(II) bis(hexafluorido-phosphate)_10.1107S2056989015003503.pdf | 988.83 kB | Adobe PDF | View/Open |
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