Utilize este identificador para referenciar este registo:
http://hdl.handle.net/10773/18219
Título: | Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]manganese(II) bis(hexafluorido-phosphate) |
Autor: | Lourenço, Leandro M. O. Almeida Paz, Filipe A. Fernandes, José A. |
Palavras-chave: | Crystal structure Metalloligand Manganese Terpyridine |
Data: | 2015 |
Editora: | International Union of Crystallography |
Resumo: | The crystal structures of bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]mangan-ese(II) bis(hexafluoridophosphate) monohydrate, [Mn(C20H14N4)2](PF6)2·-H2O, (1), and bis[4′-(pyridin-4-yl)-2,2′:6′,2″-terpyridine]manganese(II) bis-(hexafluoridophosphate) acetone monosolvate, (2), [Mn(C20H14N4)2]-(PF6)2·CH3COCH3, are described. At 150 K, (1) and (2) have monoclinic (P21/c) and orthorhombic (C2221) symmetries, respectively. Both structures exhibit octahedrally coordinated MnII atoms and disorder. They display weak interactions, such as C - H⋯F, C - H⋯N, C - H⋯π, F⋯π and π-π. The twofold rotation axis in the molecule of (2) is coincident with a twofold rotation axis of the crystal. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/18219 |
DOI: | 10.1107/S2056989015003503 |
ISSN: | 2056-9890 |
Aparece nas coleções: | CICECO - Artigos DQ - Artigos |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
Crystal structures of the water and acetone monosolvates of bis[4′-(pyridin-4-yl)-22′6′2″-terpyridine]manganese(II) bis(hexafluorido-phosphate)_10.1107S2056989015003503.pdf | 988.83 kB | Adobe PDF | Ver/Abrir |
Todos os registos no repositório estão protegidos por leis de copyright, com todos os direitos reservados.