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http://hdl.handle.net/10773/7231
Title: | Luminous efficiency enhancement of PVK based OLEDs with fac-[ClRe(CO)3(bpy)] |
Author: | Mizoguchi, Sergio Santos, Gerson Andrade, Adnei Fonseca, Fernando Pereira, Luiz Iha, Neyde |
Keywords: | Rhenium complex Phosphorescence Triplet emitter Electroluminescence PVK Organic light-emitting diode OLED |
Issue Date: | 2011 |
Publisher: | Elsevier |
Abstract: | The luminous efficiency of organic light-emitting diodes based on poly(N-vinylcarbazole), PVK, was improved by adding fac-[ClRe(CO)3(bpy)], bpy = 2,2′-bipyridine, to PVK host. Emissive layers with various Re(I) complex/host ratio were employed and optoelectronic properties were compared with the single PVK device. The single PVK device exhibits a characteristic electroluminescence with blue emission, λmax 420 nm, assigned to the PVK excimer. On the other hand, the intense and broad band at λmax 580 nm of the Re(I) complex/PVK OLEDs is ascribed to the metal-to-ligand charge transfer excited state emission of fac-[ClRe(CO)3(bpy)]. At 30 V, the device luminous efficiency increased from 16 mcd/A for the single PVK device to 211 mcd/A for the 11% (w/w) Re(I) complex/PVK OLED, in which fac-[ClRe(CO)3(bpy)] acts as an electron-trap in PVK films. The device current is space-charge limited and exhibits typical emissive layer thickness dependence |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/7231 |
DOI: | 10.1016/j.synthmet.2011.07.005 10.1016/j.synthmet.2011.07.005 |
ISSN: | 0379-6779 |
Appears in Collections: | DFis - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Complexo_Re_SynthMetals_(2011).pdf | artigo | 408.43 kB | Adobe PDF |
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