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http://hdl.handle.net/10773/35876
Title: | Employing three-blade propeller lanthanide complexes as molecular luminescent thermometers: study of temperature sensing through a concerted experimental/theory approach |
Author: | Lyubov, Dmitry M. Carneiro Neto, Albano N. Fayoumi, A. Lyssenko, K. A. Korshunov, V. M. Taydakov, I. V. Salles, F. Guari, Y. Larionova, J. Carlos, Luis D. Long, J. Trifonov, A. A. |
Issue Date: | 2022 |
Publisher: | Royal Society of Chemistry |
Abstract: | We report the synthesis, structures, magnetic and luminescence properties of a series of three-blade propeller homoleptic lanthanide complexes [LnL3](ClO4)3·H2O·2MeCN (Ln = Eu (1), Tb (2), Dy (3), Er (4), Yb (5), Gd (6); L = 2,6-bis(1-methyl-imidazol-2-yl)pyridine). The Eu, Tb, and Dy analogues exhibit the characteristic lanthanide-based luminescence. Remarkably, the mixed Eu/Tb complex with a metal ratio of 1 : 10 can be used as a ratiometric thermometer in the solid-state between 130 and 220 K with the maximum value of Sr = 6.6% K−1 within the range of 150-170 K. Theoretical calculations allow not only modelling of the luminescence properties of pure complexes but also rationalization of the performances of the mixed Eu/Tb thermometers |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/35876 |
DOI: | 10.1039/d2tc01289h |
ISSN: | 2050-7526 |
Appears in Collections: | CICECO - Artigos DFis - Artigos |
Files in This Item:
File | Description | Size | Format | |
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paper.pdf | 5.34 MB | Adobe PDF |
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