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http://hdl.handle.net/10773/21983
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DC Field | Value | Language |
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dc.contributor.author | Vyshatko, N.P. | pt |
dc.contributor.author | Kharton, V. | pt |
dc.contributor.author | Shaula, A.L. | pt |
dc.contributor.author | Naumovich, E.N. | pt |
dc.contributor.author | Marques, F.M.B. | pt |
dc.date.accessioned | 2018-01-31T18:49:57Z | - |
dc.date.available | 2018-01-31T18:49:57Z | - |
dc.date.issued | 2003-01 | - |
dc.identifier.issn | 0025-5408 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/21983 | - |
dc.description.abstract | Comparative analysis of the structure refinement results of perovskite-like LaGa0.5M0.5O3-δ (M = Mn, Fe, Co, Ni) and data on other LaGaO3-based phases, heavily doped with transition metal cations, shows that on doping the structural changes in these oxides follow common trends for the perovskite-type systems. The maximum ionic conductivity, observed in various perovskites when the tolerance factor values are approximately 0.96-0.97, was found to correlate with the transition from orthorhombic to rhombohedral structure and maximum lattice distortion. The perovskite unit cell distortion near the orthorhombic-rhombohedral phase boundary may hence play a positive role in the ionic transport processes. © 2002 Elsevier Science Ltd. All rights reserved. | pt |
dc.language.iso | eng | pt |
dc.publisher | Elsevier | pt |
dc.relation | PRAXIS and POCTI - BD/6595/2001 | pt |
dc.relation | INTAS - project 00276 | pt |
dc.rights | openAccess | por |
dc.subject | Crystal structure | pt |
dc.subject | Ionic conductivity | pt |
dc.subject | Oxides | pt |
dc.subject | X-ray diffraction | pt |
dc.subject | Approximation theory | pt |
dc.subject | Crystal structure | pt |
dc.subject | Doping (additives) | pt |
dc.subject | Ionic conduction | pt |
dc.subject | Positive ions | pt |
dc.subject | Transition metals | pt |
dc.subject | X ray diffraction | pt |
dc.subject | Structural characterization | pt |
dc.subject | Perovskite | pt |
dc.title | Structural characterization of mixed conducting perovskites La(Ga,M)O3-δ ( M = Mn, Fe, Co, Ni) | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
ua.event.title | Materials Research Bulletin | - |
degois.publication.firstPage | 185 | pt |
degois.publication.issue | 2 | - |
degois.publication.lastPage | 193 | pt |
degois.publication.title | Materials Research Bulletin | pt |
degois.publication.volume | 38 | pt |
dc.identifier.doi | 10.1016/S0025-5408(02)01050-4 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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MRB38_185.pdf | Article | 183.86 kB | Adobe PDF | View/Open |
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