Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20878
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Reddy, A. A. | pt |
dc.contributor.author | Tulyaganov, D. U. | pt |
dc.contributor.author | Pascual, M. J. | pt |
dc.contributor.author | Kharton, V. V. | pt |
dc.contributor.author | Tsipis, E. V. | pt |
dc.contributor.author | Kolotygin, V. A. | pt |
dc.contributor.author | Ferreira, J. M. F. | pt |
dc.date.accessioned | 2017-12-07T20:02:37Z | - |
dc.date.issued | 2013 | pt |
dc.identifier.issn | 1615-6846 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/20878 | - |
dc.description.abstract | A series of glasses and glass-ceramics (GCs) aiming at applications as sealants for solid oxide fuel cells (SOFCs) were synthesized by partial substitution of Ca for Sr in the diopside-Ba disilicate composition. X-ray diffraction in conjunction with the Rietveld-RIR technique were employed to quantify the crystalline (diopside and Sr-diopside) and amorphous phases in the glasses sintered/heat treated at 850 degrees C in humidified 10%H-2-90%N-2 gas mixture for 250h. Weibull modulus varied in the range 11.6-34.4 implying toward good mechanical reliability of synthesized GCs. Thermal shock resistance of model electrochemical cells made of yttria-stabilized zirconia, gadolinia-doped ceria, and lanthanum gallate based solid electrolytes, hermetically sealed by one diopside-based composition, was evaluated employing quenching from 800 degrees C in air and water. Suitable thermal expansion coefficient, mechanical reliability, and strong adhesion to stabilized zirconia and metallic interconnects, are all suggesting a good suitability of the sealants for SOFC applications. | pt |
dc.language.iso | eng | pt |
dc.publisher | WILEY-V C H VERLAG GMBH | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F89915%2F2012/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/114209/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | TRANSPORT-PROPERTIES | pt |
dc.subject | SEALING GLASS | pt |
dc.subject | ELECTROLYTES | pt |
dc.subject | INTERCONNECT | pt |
dc.subject | COMPOSITE | pt |
dc.subject | STRENGTH | pt |
dc.subject | ZIRCONIA | pt |
dc.title | SrO-Containing Diopside Glass-Ceramic Sealants for Solid Oxide Fuel Cells: Mechanical Reliability and Thermal Shock Resistance | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 689 | pt |
degois.publication.issue | 5 | pt |
degois.publication.lastPage | 694 | pt |
degois.publication.title | FUEL CELLS | pt |
degois.publication.volume | 13 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1002/fuce.201200237 | pt |
dc.identifier.doi | 10.1002/fuce.201200237 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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SrO-Containing Diopside Glass-Ceramic Sealants for Solid Oxide Fuel Cells Mechanical Reliability and Thermal Shock Resistance_10.1002fuce.201200237.pdf | 423.61 kB | Adobe PDF |
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