Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20645| Title: | Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding |
| Author: | Lim, Jason Y. C. Marques, Igor Ferreira, Liliana Felix, Vitor Beer, Paul D. |
| Keywords: | AMINO-ACIDS RECEPTORS CATALYSIS WATER ION EXPLORATION SENSORS FIELD |
| Issue Date: | 2016 |
| Publisher: | ROYAL SOC CHEMISTRY |
| Abstract: | Chiral halogen bonding (S)-BINOL-based receptors are demonstrated to enhance the enantioselective recognition and sensing of chiral anions compared to their hydrogen bonding analogues. Computational studies attribute this behaviour to the strict linearity of halogen bonding (XB) and steric environment conferred by the XB donor groups bridged by the (S)-BINOL motif. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20645 |
| DOI: | 10.1039/c6cc01701k |
| ISSN: | 1359-7345 |
| Publisher Version: | 10.1039/c6cc01701k |
| Appears in Collections: | CICECO - Artigos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding_10.1039c6cc01701k.pdf | 740.52 kB | Adobe PDF |  |
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