Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20606
Title: | A supramolecular strategy based on molecular dipole moments for high-quality covalent organic frameworks |
Author: | Salonen, Laura M. Medina, Dana D. Carbo-Argibay, Enrique Goesten, Maarten G. Mafra, Luis Guldris, Noelia Rotter, Julian M. Stroppa, Daniel G. Rodriguez-Abreu, Carlos |
Keywords: | BIOLOGICAL RECOGNITION PI INTERACTIONS AROMATIC RINGS HYDROGEN-BONDS CARBON-DIOXIDE CRYSTALLINE STABILITY STACKING PYRENE CONSTRUCTION |
Issue Date: | 2016 |
Publisher: | ROYAL SOC CHEMISTRY |
Abstract: | A supramolecular strategy based on strongmolecular dipole moments is presented to gain access to covalent organic framework structures with high crystallinity and porosity. Antiparallel alignment of the molecules within the pore walls is proposed to lead to reinforced columnar stacking, thus affording a high-quality material. As a proof of principle, a novel pyrene dione building block was prepared and reacted with hexahydroxytriphenylene to form a boronic ester-linked covalent organic framework. We anticipate the strategy presented herein to be valuable for producing highly defined COF structures. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20606 |
DOI: | 10.1039/c6cc02170k |
ISSN: | 1359-7345 |
Publisher Version: | 10.1039/c6cc02170k |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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A supramolecular strategy based on molecular dipole moments for high-quality covalent organic frameworks_10.1039c6cc02170k.pdf | 918.95 kB | Adobe PDF |
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