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http://hdl.handle.net/10773/20545
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gomes, Ana C. | pt |
dc.contributor.author | Pillinger, Martyn | pt |
dc.contributor.author | Nunes, Patrique | pt |
dc.contributor.author | Goncalves, Isabel S. | pt |
dc.contributor.author | Abrantes, Marta | pt |
dc.date.accessioned | 2017-12-07T19:50:54Z | - |
dc.date.issued | 2014 | pt |
dc.identifier.issn | 0022-328X | pt |
dc.identifier.uri | http://hdl.handle.net/10773/20545 | - |
dc.description.abstract | The compounds MoO2Cl2L (L = 2,2'-bipyridine (bipy) (1); 4,4'-di-tert-butyl-2,2'-bipyridine (di-Bu-t-bipy) (2)), [MoO2Cl2(H2O)(2)]center dot(diglyme)(2) (3), MoO2Cl2 (4), MoO2(CH3)(2)L (L bipy (5); di-Bu-t-bipy (6)), [MoO3(bipy)] n (7), {[MoO3(bipy)][MoO3(H2O)]} n (8), [Mo8O22(OH)(4)(di-Bu-t-bipy)(4)] (9) and MoO3 (10) were tested as phosphoester bond hydrolysis promoters in aqueous media. Sodium para-nitrophenylphosphate (pNPP) was used as a model substrate for the phosphoester bond hydrolysis reaction, which was performed at 55 degrees C, using D2O as solvent and 100 or 10 mol% of the chosen promoter. The progression of all the reactions was monitored by H-1 NMR spectroscopy. All studied systems promote phosphoester bond hydrolysis. The best performance was obtained with MoO2Cl2L compounds (1-4) and with the inorganiceorganic hybrid {[MoO3(bipy)][MoO3(H2O)]}(n) (8). The studied compounds originate either homogeneous or solid/liquid biphasic systems. For the biphasic systems (1, 2, 5-9), the solid phase was recovered at the end of the reaction and characterized by FT-IR spectroscopy. (C) 2014 Elsevier B. V. All rights reserved. | pt |
dc.language.iso | eng | pt |
dc.publisher | ELSEVIER SCIENCE SA | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/3599-PPCDT/132962/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/127348/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/3599-PPCDT/126438/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | CYCLOOCTENE EPOXIDATION | pt |
dc.subject | ORGANOMETALLIC COMPLEX | pt |
dc.subject | CATALYTIC APPLICATIONS | pt |
dc.subject | BOND-CLEAVAGE | pt |
dc.subject | MOLYBDATE | pt |
dc.subject | POLYOXOMOLYBDATE | pt |
dc.subject | PERFORMANCE | pt |
dc.subject | PRECURSORS | pt |
dc.subject | PHOSPHATE | pt |
dc.subject | OLEFINS | pt |
dc.title | Promotion of phosphoester hydrolysis by MoO2Cl2L (L bipyridine derivatives, H2O, no ligand), MoO2(CH3)(2)L (L bipyridine derivatives) and related inorganice-organic hybrids in aqueous media | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 42 | pt |
degois.publication.lastPage | 47 | pt |
degois.publication.title | JOURNAL OF ORGANOMETALLIC CHEMISTRY | pt |
degois.publication.volume | 760 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1016/j.jorganchem.2013.12.029 | pt |
dc.identifier.doi | 10.1016/j.jorganchem.2013.12.029 | pt |
Appears in Collections: | CICECO - Artigos |
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