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http://hdl.handle.net/10773/20498| Title: | On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate |
| Author: | Isabel Cabaco, M. Besnard, Marcel Chavez, Fabian Vaca Pinaud, Noel Sebastiao, Pedro J. Coutinho, Joao A. P. Mascetti, Joelle Danten, Yann |
| Keywords: | IONIC LIQUIDS CO2 SULFIDE DITHIOCARBOXYLATES COMPLEXES SYSTEMS PHASE |
| Issue Date: | 2013 |
| Publisher: | ROYAL SOC CHEMISTRY |
| Abstract: | Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C(4)mim] [Ac] in the liquid phase. The formation of [C(4)mim] CO2, [C(4)mim] COS, CH3COS- and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not observed in the CO2-[C(4)mim] [Ac] reaction. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20498 |
| DOI: | 10.1039/c3cc46038j |
| ISSN: | 1359-7345 |
| Publisher Version: | 10.1039/c3cc46038j |
| Appears in Collections: | CICECO - Artigos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate_10.1039c3cc46038j.pdf | 814.04 kB | Adobe PDF |  |
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