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http://hdl.handle.net/10773/19693
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DC Field | Value | Language |
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dc.contributor.author | Yasakau, K. A. | pt |
dc.contributor.author | Carneiro, J. | pt |
dc.contributor.author | Zheludkevich, M. L. | pt |
dc.contributor.author | Ferreira, M. G. S. | pt |
dc.date.accessioned | 2017-12-07T19:21:42Z | - |
dc.date.issued | 2014 | pt |
dc.identifier.issn | 0257-8972 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/19693 | - |
dc.description.abstract | The present work explores effects of shelf-life, temperature and the presence of cerium nitrate additive on the protective performance of sol-gel coatings applied on AA2024. These are important parameters when industrial applicability of coating formulations is considered. The studied sol-gel system is based on a combination of metalorganic precursor titanium(IV) propoxide and hybrid epoxy silane 3-glycidoxypropyltrimethoxysilane. The synthesized sol-gel formulations without or with addition of 0.007 M Ce(NO3)(3) were aged during different times at temperatures 25 degrees C or 6 degrees C. FTIR results show that the intensities of the bands associated to Si- O-Si increase with respect to Si-OH groups during the aging process as a result of extended condensation. However, such transformations occur less rapidly at low temperature. The electrochemical impedance spectroscopy measurements clearly show that sol-gel coatings corresponding to the sol-gel aged at low temperature exhibit similar corrosion protective capabilities compared to the coating obtained without sol-gel aging. It is also observed that the protection performance of the sol-gel coatings with cerium nitrate obtained after two weeks of sol-gel aging is lower compared to the coatings without cerium additive. This effect is attributed to the enhanced reactivity of the sol-gel due to cerium(III) presence. (C) 2014 Elsevier B.V. All rights reserved. | pt |
dc.language.iso | eng | pt |
dc.publisher | ELSEVIER SCIENCE SA | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F80754%2F2011/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | CORROSION PROTECTION | pt |
dc.subject | CERIUM CONCENTRATION | pt |
dc.subject | CONVERSION COATINGS | pt |
dc.subject | ALUMINUM 2024-T3 | pt |
dc.subject | ALLOYS | pt |
dc.subject | PERFORMANCE | pt |
dc.subject | INHIBITION | pt |
dc.subject | CONDENSATION | pt |
dc.subject | CAPACITANCE | pt |
dc.subject | CHROMATE | pt |
dc.title | Influence of sol-gel process parameters on the protection properties of sol-gel coatings applied on AA2024 | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 6 | pt |
degois.publication.lastPage | 16 | pt |
degois.publication.title | SURFACE & COATINGS TECHNOLOGY | pt |
degois.publication.volume | 246 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1016/j.surfcoat2014.02.038 | pt |
dc.identifier.doi | 10.1016/j.surfcoat2014.02.038 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Influence of sol-gel process parameters on the protection properties of sol-gel coatings applied on AA2024_10.1016j.surfcoat2014.02.038.pdf | 1.01 MB | Adobe PDF |
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