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http://hdl.handle.net/10773/19682
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yang, Ting-Hai | pt |
dc.contributor.author | Ferreira, Rute A. S. | pt |
dc.contributor.author | Carlos, Luis D. | pt |
dc.contributor.author | Rocha, Joao | pt |
dc.contributor.author | Shi, Fa-Nian | pt |
dc.date.accessioned | 2017-12-07T19:21:21Z | - |
dc.date.available | 2017-12-07T19:21:21Z | - |
dc.date.issued | 2014 | pt |
dc.identifier.issn | 2046-2069 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/19682 | - |
dc.description.abstract | Reaction of lanthanide oxides, cadmium acetate and 3,5-pyrazoledicarboxylic acid under hydrothermal conditions afforded five new isostructural 4d-4f hetero-metal organic frameworks, [Cd(3)Ln(pdc)(3)(H2O)] {H(3)pdc = 3,5-pyrazoledicarboxylic acid, Ln = La (1), Pr (2), Nd (3), Sm (4) and Eu (5)}. All compounds were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. The compounds feature a very interesting 3D structure built up from a secondary building unit, [Cd(12)Ln(8)(pdc)(6)], and possess a new topology type and complicated unique tiling. The solid state photoluminescence properties of compounds 3-5 were investigated at room temperature. | pt |
dc.language.iso | eng | pt |
dc.publisher | ROYAL SOC CHEMISTRY | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F74582%2F2010/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/119994/PT | pt |
dc.rights | openAccess | por |
dc.subject | HETEROMETALLIC COORDINATION POLYMERS | pt |
dc.subject | CU(II)LN(III) DINUCLEAR UNITS | pt |
dc.subject | SINGLE-MOLECULE MAGNET | pt |
dc.subject | INORGANIC SUBNETWORK | pt |
dc.subject | BUILDING-BLOCKS | pt |
dc.subject | EXTENDED ARRAYS | pt |
dc.subject | COMPLEXES LN | pt |
dc.subject | LUMINESCENCE | pt |
dc.subject | CLUSTER | pt |
dc.subject | ACID | pt |
dc.title | Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 7818 | pt |
degois.publication.issue | 15 | pt |
degois.publication.lastPage | 7825 | pt |
degois.publication.title | RSC ADVANCES | pt |
degois.publication.volume | 4 | pt |
dc.relation.publisherversion | 10.1039/c3ra47686c | pt |
dc.identifier.doi | 10.1039/c3ra47686c | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Crystal structure topology tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 35-pyrazoledicaboxylate_10.1039c3ra47686c.pdf | 921.25 kB | Adobe PDF | View/Open |
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