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http://hdl.handle.net/10773/19449
Title: | Chiral periodic mesoporous copper(II) bis(oxazoline) phenylene-silica: A highly efficient and reusable asymmetric heterogeneous catalyst |
Author: | Lourenco, Mirtha A. O. Carneiro, Liliana Mayoral, Alvaro Diaz, Isabel Silva, Ana R. Ferreira, Paula |
Keywords: | ENANTIOSELECTIVE CATALYSIS KINETIC RESOLUTION CARBON REPLICAS ORGANOSILICA COMPLEXES LIGANDS SUPPORT CYCLOPROPANATION IMMOBILIZATION BISOXAZOLINES |
Issue Date: | 2014 |
Publisher: | ACADEMIC PRESS INC ELSEVIER SCIENCE |
Abstract: | We describe the preparation of an effective and reusable heterogeneous asymmetric catalyst. A novel chiral periodic mesoporous phenylene-silica containing high density of bis(oxazoline) moieties is prepared by co-condensation method with 1,4-bis(triethoxysilyl)benzene. After copper(II) coordination, the material is extremely efficient on the kinetic resolution of the 1,2-diphenylethane-1,2-diol with persistent high enantioselectivities (91 - > 99%) and yields (46-43% in maximum 50% resolution) at least for five consecutive cycles. Characterization of the material after the catalytic experiments showed that the heterogeneous catalyst was very robust keeping the integrity of the structure. (C) 2014 Elsevier Inc. All rights reserved. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19449 |
DOI: | 10.1016/j.jcat.2014.09.017 |
ISSN: | 0021-9517 |
Publisher Version: | 10.1016/j.jcat.2014.09.017 |
Appears in Collections: | CICECO - Artigos |
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Chiral periodic mesoporous copper(II) bis(oxazoline) phenylene.silica A highly efficient and reusable asymmetric heterogeneous catalyst_10.1016j.jcat.2014.09.017.pdf | 613.98 kB | Adobe PDF |
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