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http://hdl.handle.net/10773/19321
Title: | Structural, physical and chemical properties of nanostructured nickel-substituted ceria oxides under reducing and oxidizing conditions |
Author: | Fuentes, R. O. Acuna, L. M. Albornoz, C. A. Leyva, A. G. Sousa, N. Figueiredo, F. M. |
Keywords: | DOPED CERIA NANOPARTICLES CATALYSTS METHANE REDUCTION EXPANSION OXIDATION NIO/CEO2 BEHAVIOR METAL |
Issue Date: | 2016 |
Publisher: | ROYAL SOC CHEMISTRY |
Abstract: | This work reports the synthesis of nanostructured Ce1-xNixO2-delta (x = 0.05, 0.1, 0.15 and 0.2) oxides prepared by a cation complexation route and with the main objective of studying their redox properties using a combination of electron microscopy, synchrotron radiation X-ray diffraction (SR-XRD) and X-ray absorption near-edge spectroscopy (XANES). The Ce1-xNixO2-delta series of nanopowders maintain the cubic crystal structure (Fm3m space group) of pure ceria, with an average crystallite size of 5-7 nm indicated by XRD patterns and confirmed by transmission electron microscopy. In situ SR-XRD and XANES carried out under reducing (5% H-2/He; 5% CO/He) and oxidizing (21% O-2/N-2) atmospheres at temperatures up to 500 degrees C show a Ni solubility limit close to 15 at% in air at room temperature, decreasing to about 10 at% after exposure to 5% H-2/He atmosphere at 500 degrees C. At room temperature in air, the effect of Ni on the lattice parameter of Ce1-xNixO2-delta is negligible, whereas a marked expansion of the lattice is observed at 500 degrees C in reducing conditions. This is shown by XANES to be correlated with the reduction of up to 25% of Ce4+ cations to the much larger Ce3+, possibly accompanied by the formation of oxygen vacancies. The redox ability of the Ce4+/Ce3+ couple in nanocrystalline Ni-substituted ceria is greatly enhanced in comparison to pure ceria or achieved by using other dopants (e.g. Gd, Tb or Pr), where it is limited to less than 5% of Ce cations. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19321 |
DOI: | 10.1039/c6ra14853k |
ISSN: | 2046-2069 |
Publisher Version: | 10.1039/c6ra14853k |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Structural physical and chemical properties of nanostructured nickel-substituted ceria oxides under reducing and oxidizing conditions_10.1039c6ra14853k.pdf | 2.39 MB | Adobe PDF | View/Open |
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