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http://hdl.handle.net/10773/19289
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yang, Ting-Hai | pt |
dc.contributor.author | Silva, Ana Rosa | pt |
dc.contributor.author | Shi, Fa-Nian | pt |
dc.date.accessioned | 2017-12-07T19:07:34Z | - |
dc.date.issued | 2013 | pt |
dc.identifier.issn | 1477-9226 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/19289 | - |
dc.description.abstract | Reactions of lanthanide chlorides, copper hydroxycarbonate and 3,5-pyrazole dicarboxylic acid (H(3)pdc) under hydrothermal conditions result in six new 3d-4f heterometallic coordination polymers with two types of structures. Compounds [CuLn(2)(pdc)(2)(Hpdc)(H2O)(4)]center dot 2H(2)O (Ln = Tb (1), Dy (2), Er (3), and Y (4) exhibit a layered porous structure, made up of Cu(II)Ln(III) di-nuclear units which are connected by protonated Hpdc(2-) ligand, while the others [Cu(3)Ln(4)(pdc)(6)(H2O)(8)] (Ln = Eu (5), Gd (6)) display a three-dimensional (3-D) framework structure, in which six Cu(II)Ln(III) di-nuclear units are cross-linked by two coordinated lanthanide atoms. The catalytic properties of 3 are investigated showing its activity and recyclability in the reaction of cyclopropanation of styrene. | pt |
dc.language.iso | eng | pt |
dc.publisher | ROYAL SOC CHEMISTRY | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F74582%2F2010/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/119994/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | METAL-ORGANIC FRAMEWORKS | pt |
dc.subject | SINGLE-MOLECULE MAGNET | pt |
dc.subject | INORGANIC SUBNETWORK | pt |
dc.subject | COMPLEXES | pt |
dc.subject | LIGAND | pt |
dc.subject | CLUSTERS | pt |
dc.subject | LN | pt |
dc.subject | RELAXATION | pt |
dc.subject | CATALYSIS | pt |
dc.subject | SULFATE | pt |
dc.title | Six new 3d-4f heterometallic coordination polymers constructed from pyrazole-bridged Cu(II)Ln(III) dinuclear units | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 13997 | pt |
degois.publication.issue | 38 | pt |
degois.publication.lastPage | 14005 | pt |
degois.publication.title | DALTON TRANSACTIONS | pt |
degois.publication.volume | 42 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1039/c3dt51015h | pt |
dc.identifier.doi | 10.1039/c3dt51015h | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Six new 3d–4f heterometallic coordination polymers constructed from pyrazole-bridged CuIILnIII dinuclear units_10.1039c3dt51015h.pdf | 2.71 MB | Adobe PDF |
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