Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20588
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shi, Fa-Nian | pt |
dc.contributor.author | Silva, Ana Rosa | pt |
dc.contributor.author | Bian, Liang | pt |
dc.date.accessioned | 2017-12-07T19:52:28Z | - |
dc.date.issued | 2015 | pt |
dc.identifier.issn | 0022-4596 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/20588 | - |
dc.description.abstract | A new terminology of metal organic oxide (MOO) was given a definition as a type of coordination polymers which possess the feature of inorganic connectivity between metals and the direct bonded atoms and show 1D, 2D or 3D inorganic sub-networks. One such compound was shown as an example. A 3d-6p (Mn-Bi. Named MOOMnBi) mixed metals coordination network has been synthesized via hydrothermal method. The new compound with the molecular formula of [MnBi2O(1,3,5-BTC)(2)](n). (1,3,5-BTC stands for benzene-1,3,5-tricarboxylate) was characterized via single crystal X-ray diffraction technique that revealed a very interesting 3-dimensional (3D) framework with Bi4O2(COO)(12) clusters which are further connected to Mn(COO)(6) fragments into a 2D MOO. The topology study indicates an unprecedented topological type with the net point group of (4(13).6(2)){4(13).6(8))(4(16).6(5))(4(18).6(10)){4(22).6(14)}(4(3)) corresponding to 3,6,7,7,8,9-c hexa-nodal net. MOOMnBi shows catalytic activity in the synthesis of (E)-alpha,beta-unsaturated ketones. (C) 2014 Elsevier Inc. All rights reserved. | pt |
dc.language.iso | eng | pt |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/119994/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147332/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | INORGANIC CONNECTIVITY | pt |
dc.subject | MAGNETIC-PROPERTIES | pt |
dc.subject | CRYSTAL-STRUCTURE | pt |
dc.subject | FRAMEWORKS | pt |
dc.subject | HYBRID | pt |
dc.subject | POLYMERS | pt |
dc.subject | MANGANESE | pt |
dc.subject | ACID | pt |
dc.subject | PHOTOLUMINESCENCE | pt |
dc.subject | 4,4'-BIPYRIDINE | pt |
dc.title | Bi-Mn mixed metal organic oxide: A novel 3d-6p mixed metal coordination network | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 45 | pt |
degois.publication.lastPage | 52 | pt |
degois.publication.title | JOURNAL OF SOLID STATE CHEMISTRY | pt |
degois.publication.volume | 225 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1016/j.jssc.2014.11.027 | pt |
dc.identifier.doi | 10.1016/j.jssc.2014.11.027 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Bi-Mn mixed metal organic oxide A novel 3d-6p mixed metal coordination network_10.1016j.jssc.2014.11.027.pdf | 2.44 MB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.