Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/20125
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Magalhaes, Ana L. | pt |
dc.contributor.author | Lito, Patricia F. | pt |
dc.contributor.author | Da Silva, Francisco A. | pt |
dc.contributor.author | Silva, Carlos M. | pt |
dc.date.accessioned | 2017-12-07T19:36:19Z | - |
dc.date.issued | 2013 | pt |
dc.identifier.issn | 0896-8446 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/20125 | - |
dc.description.abstract | The binary diffusion coefficients at infinite dilution, D-12, are fundamental properties in chemical engineering simulation and design. In this work, very simple and accurate expressions involving two parameters are proposed/analyzed for their estimation. They depend only on temperature and/or solvent density and/or solvent viscosity. Their correlation and prediction abilities are tested with the largest database ever compiled, composed of 539 binary systems and 8219 data points, where polar/non-polar, symmetrical/asymmetrical, small/large, and light/heavy molecules are included without exception. It is shown that only two experimental D-12 values are sufficient to get good parameters for the subsequent estimation of reliable diffusivities far away from the conditions of the experimental data utilized to fit them. Globally, Eqs. (2)-(4) and (9) are recommended for D-12 calculation, due to the excellent results achieved for both correlation (average errors between 2.78% and 3.05%) and prediction (average errors between 4.21% and 4.44%). A comparison with models from the literature is also accomplished. (C) 2013 Elsevier B.V. All rights reserved. | pt |
dc.language.iso | eng | pt |
dc.publisher | ELSEVIER SCIENCE BV | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBD%2F46776%2F2008/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F63214%2F2009/PT | pt |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/228589/EU | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132936/PT | pt |
dc.rights | restrictedAccess | por |
dc.subject | TAYLOR DISPERSION TECHNIQUE | pt |
dc.subject | IMPULSE-RESPONSE METHOD | pt |
dc.subject | LENNARD-JONES FLUID | pt |
dc.subject | LIMITING INTERDIFFUSION COEFFICIENTS | pt |
dc.subject | AQUEOUS ALKANOLAMINE SOLUTIONS | pt |
dc.subject | SLIGHTLY SOLUBLE GASES | pt |
dc.subject | PARTIAL MOLAR VOLUMES | pt |
dc.subject | ACID METHYL-ESTERS | pt |
dc.subject | ALPHA-AMINO-ACIDS | pt |
dc.subject | RHO-T DATA | pt |
dc.title | Simple and accurate correlations for diffusion coefficients of solutes in liquids and supercritical fluids over wide ranges of temperature and density | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 94 | pt |
degois.publication.lastPage | 114 | pt |
degois.publication.title | JOURNAL OF SUPERCRITICAL FLUIDS | pt |
degois.publication.volume | 76 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.relation.publisherversion | 10.1016/j.supflu.2013.02.002 | pt |
dc.identifier.doi | 10.1016/j.supflu.2013.02.002 | pt |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.