Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/19906
Title: | A Tetranuclear Silver-Thiourea Cluster |
Author: | Fernandes, José A. Segura, Daniel F. Netto, Adelino V. G. Frem, Regina C. G. Mauro, Antonio E. Almeida Paz, Filipe A. |
Keywords: | X-RAY-STRUCTURE CRYSTAL-STRUCTURE AMINO-ACIDS COMPLEXES LIGAND SALTS 1,10-PHENANTHROLINE ETHYLENETHIOUREA DERIVATIVES RESISTANCE |
Issue Date: | 2015 |
Publisher: | SPRINGER/PLENUM PUBLISHERS |
Abstract: | During the synthesis of the bioactive complex [Ag(phen)(mu-tu)](2)(NO3)(2) (1), some crystals of a new compound were isolated. This crystalline compound, [Ag-4(mu-tu)(5)(tu)(6)](NO3)(4)center dot 7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities. The new compound [Ag-4(mu-tu)(5)(tu)(6)](NO3)(4)center dot 7Phen (tu = thiourea, Phen = 1,10-phenanthroline) is a novelty at least by two ways: (i) it is the first tetranuclear cluster of silver and thiourea; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. [GRAPHICS] . |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/19906 |
DOI: | 10.1007/s10870-015-0608-9 |
ISSN: | 1074-1542 |
Publisher Version: | 10.1007/s10870-015-0608-9 |
Appears in Collections: | CICECO - Artigos DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
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A Tetranuclear Silver-Thiourea Cluster_10.1007s10870-015-0608-9.pdf | 1.57 MB | Adobe PDF |
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