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http://hdl.handle.net/10773/19510
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Liu, Bing | pt |
dc.contributor.author | Fernandes, Jose A. | pt |
dc.contributor.author | Tome, Joao P. C. | pt |
dc.contributor.author | Almeida Paz, Filipe A. | pt |
dc.contributor.author | Cunha-Silva, Luis | pt |
dc.date.accessioned | 2017-12-07T19:15:13Z | - |
dc.date.available | 2017-12-07T19:15:13Z | - |
dc.date.issued | 2015 | pt |
dc.identifier.issn | 1420-3049 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/19510 | - |
dc.description.abstract | The synthesis and structural characterization of five transition metal complexes with different dimensionality and incorporating residues of 3-amino-1H-1,2,4-triazole-5-carboxylic acid (H(2)atrc) is reported: [Zn(Hatrc)(2)(H2O)] (1), [Mn(Hatrc)(2)(H2O)(2)]center dot 2H(2)O (2), [Fe-2(Hatrc)(4)(OH)(2)]center dot 6H(2)O (3), [Cd(Hatrc)(2)(H2O)](n) (4), and [Mn(atrc)(H2O)](n)center dot nH(2)O (5). These materials could be prepared from solution (1-3), diffusion (4), or hydrothermal reactions (5) with various anions and L:M ratios. Structural details were revealed by single crystal X-ray diffraction. The discrete units composing compounds 1-3, the polymeric 1D chain of 4 and the 2D layer of 5 are further extended into 3D supramolecular architectures through the formation of hydrogen bonds. | pt |
dc.language.iso | eng | pt |
dc.publisher | MDPI AG | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147332/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147218/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/5876-PPCDTI/133035/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F63736%2F2009/PT | pt |
dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F47566%2F2008/PT | pt |
dc.rights | openAccess | por |
dc.subject | COORDINATION POLYMERS | pt |
dc.subject | ORGANIC FRAMEWORKS | pt |
dc.subject | SPIN-CROSSOVER | pt |
dc.subject | CRYSTAL | pt |
dc.subject | CHEMISTRY | pt |
dc.subject | LIGANDS | pt |
dc.subject | DESIGN | pt |
dc.title | Multidimensional Transition Metal Complexes Based on 3-Amino-1H-1,2,4-triazole-5-carboxylic Acid: From Discrete Mononuclear Complexes to Layered Materials | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 12341 | pt |
degois.publication.issue | 7 | pt |
degois.publication.lastPage | 12363 | pt |
degois.publication.title | MOLECULES | pt |
degois.publication.volume | 20 | pt |
dc.relation.publisherversion | 10.3390/molecules200712341 | pt |
dc.identifier.doi | 10.3390/molecules200712341 | pt |
Appears in Collections: | CICECO - Artigos |
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