Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/6022
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dc.contributor.authorShi, FNpt
dc.contributor.authorPaz, FAApt
dc.contributor.authorRocha, Jpt
dc.contributor.authorKlinowski, Jpt
dc.contributor.authorTrindade, Tpt
dc.date.accessioned2012-02-08T11:15:12Z-
dc.date.issued2004-08-
dc.identifier.issn1434-1948pt
dc.identifier.urihttp://hdl.handle.net/10773/6022-
dc.description.abstractA novel phosphovanadate layered structure intercalated by 4,4 -bipyridinium cations, (C10H10N2)[(VO2)4(PO4)2], was synthesised under hydrothermal conditions and its crystal structure determined using single-crystal X-ray diffraction. The anionic [(VO2)4(PO4)2]n 2n− perforated layers are strongly hydrogen bonded to the interlayer 4,4 -bipyridinium cations and are assembled by an unprecedented secondary tetrametallic VV building unit constructed from a distorted cubanelike {V4O4} cluster. The compound was further characterised by IR, Raman, 1H, 1H-13C, 31P and 51V MAS NMR spectroscopy, and by thermal and elemental analysis.pt
dc.language.isoengpt
dc.publisherWiley-VCH Verlag Berlinpt
dc.relationdx.doi.org/10.1002/ejic.200400249pt
dc.rightsrestrictedAccesspor
dc.subjectOrganic-inorganic hybridpt
dc.subjectHydrothermal synthesispt
dc.subjectOxo ligandspt
dc.subjectVanadiumpt
dc.titleNovel phosphovanadate layered structure assembled from a tetrametallic cubane-like V-v clusterpt
dc.typearticlept
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage3031pt
degois.publication.issue15
degois.publication.issue15pt
degois.publication.lastPage3037pt
degois.publication.titleEuropean Journal of Inorganic Chemistrypt
degois.publication.volume2004pt
dc.date.embargo10000-01-01-
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