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http://hdl.handle.net/10773/6022
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shi, Fa-Nian | pt |
dc.contributor.author | Almeida Paz, Filipe A. | pt |
dc.contributor.author | Rocha, João | pt |
dc.contributor.author | Klinowski, Jacek | pt |
dc.contributor.author | Trindade, Tito | pt |
dc.date.accessioned | 2012-02-08T11:15:12Z | - |
dc.date.issued | 2004-08 | - |
dc.identifier.issn | 1434-1948 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/6022 | - |
dc.description.abstract | A novel phosphovanadate layered structure intercalated by 4,4 -bipyridinium cations, (C10H10N2)[(VO2)4(PO4)2], was synthesised under hydrothermal conditions and its crystal structure determined using single-crystal X-ray diffraction. The anionic [(VO2)4(PO4)2]n 2n− perforated layers are strongly hydrogen bonded to the interlayer 4,4 -bipyridinium cations and are assembled by an unprecedented secondary tetrametallic VV building unit constructed from a distorted cubanelike {V4O4} cluster. The compound was further characterised by IR, Raman, 1H, 1H-13C, 31P and 51V MAS NMR spectroscopy, and by thermal and elemental analysis. | pt |
dc.language.iso | eng | pt |
dc.publisher | Wiley-VCH Verlag Berlin | pt |
dc.rights | restrictedAccess | por |
dc.subject | Organic-inorganic hybrid | pt |
dc.subject | Hydrothermal synthesis | pt |
dc.subject | Oxo ligands | pt |
dc.subject | Vanadium | pt |
dc.title | Novel phosphovanadate layered structure assembled from a tetrametallic cubane-like V-v cluster | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 3031 | pt |
degois.publication.issue | 15 | pt |
degois.publication.lastPage | 3037 | pt |
degois.publication.title | European Journal of Inorganic Chemistry | pt |
degois.publication.volume | 2004 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.identifier.doi | 10.1002/ejic.200400249 | pt_PT |
Appears in Collections: | CICECO - Artigos DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Eur. J. Inorg. Chem. 2004, 3031-3037.pdf | 300.79 kB | Adobe PDF |
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