Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/5993
Title: Aerosol-assisted metallo-organic chemical vapour deposition of Bi2Se3 films using single-molecule precursors: the crystal structure of bismuth(m) dibutyldiselenocarbamate
Author: Monteiro, OC
Trindade, T
Paz, FAA
Klinowski, J
Waters, J
O'Brien, P
Issue Date: 2003
Publisher: Royal Society of Chemistry
Abstract: The complexes [Bi{Se2CN(C2H5)2}3], [Bi{Se2CN(C4H9)2}3], [Bi{Se2CN(CH3)(C4H9)}3] and [Bi{Se2CN(CH3)(C6H13)}3] have been synthesized and characterized structurally using IR, 1H and 13C NMR. In addition, the crystal structure of [Bi{Se2CN(C4H9)2}3] was determined by single-crystal X-ray diffraction, showing the bismuth centre coordinated to three dialkyldiselenocarbamate ligands through the selenium donor atoms. The Bi(III) compounds were used as precursors for the deposition of Bi2Se3 films on glass substrates through aerosol-assisted metallo-organic chemical vapour deposition (AA-MOCVD).
Peer review: yes
URI: http://hdl.handle.net/10773/5993
ISSN: 0959-9428
Appears in Collections:DQ - Artigos

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