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Title: Hydro-ionothermal synthesis of lanthanide-organic frameworks with 1,4-phenylenebis(methylene)diphosphonate
Author: Shi, Fa-Nian
Trindade, Tito
Rocha, João
Paz, Filipe A. Almeida
Issue Date: Nov-2008
Publisher: American Chemical Society
Abstract: A synthetic approach combining hydrothermal and ionothermal (eutectic mixture of choline chloride and malonic acid) procedures is proposed that allowed the isolation of the first lanthanide-organic frameworks with residues of 1,4-phenylenebis(methylene)- diphosphonic acid (H4pmd), [Ln(Hpmd)(H2O)] (where Ln3+ ) Ce3+ and Pr3+), exhibiting an unprecedented trinodal topology with 3- and 8-connected nodes. The structural details were unveiled from single-crystal X-ray diffraction and the materials were characterized using standard techniques.
Peer review: yes
ISSN: 1528-7483
Appears in Collections:DQ - Artigos

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