Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/5889
Title: | Hydro-ionothermal synthesis of lanthanide-organic frameworks with 1,4-phenylenebis(methylene)diphosphonate |
Author: | Shi, Fa-Nian Trindade, Tito Rocha, João Almeida Paz, Filipe A. |
Issue Date: | Nov-2008 |
Publisher: | American Chemical Society |
Abstract: | A synthetic approach combining hydrothermal and ionothermal (eutectic mixture of choline chloride and malonic acid) procedures is proposed that allowed the isolation of the first lanthanide-organic frameworks with residues of 1,4-phenylenebis(methylene)- diphosphonic acid (H4pmd), [Ln(Hpmd)(H2O)] (where Ln3+ ) Ce3+ and Pr3+), exhibiting an unprecedented trinodal topology with 3- and 8-connected nodes. The structural details were unveiled from single-crystal X-ray diffraction and the materials were characterized using standard techniques. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/5889 |
DOI: | 10.1021/cg800639x |
ISSN: | 1528-7483 |
Appears in Collections: | CICECO - Artigos DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Crystal Growth & Design, Vol. 8, No. 11, 2008.pdf | 943.21 kB | Adobe PDF | View/Open |
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