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http://hdl.handle.net/10773/5744
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sousa, Filipa L. | pt |
dc.contributor.author | Almeida Paz, Filipe A. | pt |
dc.contributor.author | Soares-Santos, Paula C. R. | pt |
dc.contributor.author | Cavaleiro, Ana M. V. | pt |
dc.contributor.author | Nogueira, Helena I. S. | pt |
dc.contributor.author | Klinowski, Jacek | pt |
dc.contributor.author | Trindade, T. | pt |
dc.date.accessioned | 2012-02-03T13:11:07Z | - |
dc.date.issued | 2004-02 | - |
dc.identifier.issn | 0022-2860 | pt |
dc.identifier.uri | http://hdl.handle.net/10773/5744 | - |
dc.description.abstract | A novel supramolecular compound of europium(III), {[Eu(CH3OH)6(H2O)2][PMo12O40]}·(C14H20O5)2·(CH3OH)2·(CH3CN)2 (1) (where C14H20O5 is benzo-15-crown-5), was synthesised and structurally characterized by single-crystal X-ray diffraction, FT-IR, FT-Raman, 1H and 13C NMR, 31P MAS NMR and elemental analysis. Compound 1 crystallizes in the triclinic space group, with a=13.821(3), b=15.417(3), c=20.786(4) Å, α=96.10(3), β=99.79(3) and γ=91.17(3)°, V=4336.6(15) Å3, Z=2 and R1(wR2)=0.0894(0.2346). | pt |
dc.description.sponsorship | FCT - SFRH/BD/3024/2000 | pt |
dc.description.sponsorship | FEDER - POCTI/35378/QUI/2000 | pt |
dc.language.iso | eng | pt |
dc.publisher | Elsevier | pt |
dc.rights | restrictedAccess | por |
dc.subject | Polyoxometalates | pt |
dc.subject | Crown ether | pt |
dc.subject | Europium compounds | pt |
dc.subject | Crystal structure | pt |
dc.title | Synthesis, characterization and crystal structure of a novel europium(III) supramolecular compound: {[Eu(CH3OH)(6)(H2O)(2)] [PMo12O40]} (C14H20O5)(2) (CH3OH)(2) (CH3CN)(2) | pt |
dc.type | article | pt |
dc.peerreviewed | yes | pt |
ua.distribution | international | pt |
degois.publication.firstPage | 61 | pt |
degois.publication.issue | 1-2 | pt |
degois.publication.lastPage | 67 | pt |
degois.publication.title | Journal of Molecular Structure | pt |
degois.publication.volume | 689 | pt |
dc.date.embargo | 10000-01-01 | - |
dc.identifier.doi | 10.1016/j.molstruc.2003.10.020 | pt_PT |
Appears in Collections: | CICECO - Artigos DQ - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Journal of Molecular Structure 689 (2004) 61–67.pdf | 421.23 kB | Adobe PDF |
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