Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/36772
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dc.contributor.authorSimões, R.pt_PT
dc.contributor.authorRodrigues, J.pt_PT
dc.contributor.authorGranadeiro, C.M.pt_PT
dc.contributor.authorRino, L.pt_PT
dc.contributor.authorNeto, V.pt_PT
dc.contributor.authorMonteiro, T.pt_PT
dc.contributor.authorGonçalves, G.pt_PT
dc.date.accessioned2023-03-31T13:28:01Z-
dc.date.available2023-03-31T13:28:01Z-
dc.date.issued2022-11-23-
dc.identifier.urihttp://hdl.handle.net/10773/36772-
dc.description.abstractLuminescent lanthanide metal-organic frameworks (LnMOF) are gathering much interest in the scientific community due to their exceptional optical properties, which have the potential to revolutionize several application fields, including anti-counterfeiting. The traceability of the original products is an ever- growing demand for producers and end-users to verify the authenticity of produced goods. Following this newfound need, we propose an anti-counterfeiting method based on a quick-response (QR) code, with a very specific verification procedure, using a luminescent LnMOF-based composite. The embedded code will only react to certain stimulation, hence it can only be unlocked using the sequence that is programmed to respond to. For that purpose, we explored the incorporation of fresh LnMOFs, with europium (EuMOF) and terbium (TbMOF), on a biodegradable polymer matrix of polylactic acid (PLA). A homogeneous mixture of PLA/LnMOF was produced via a two-step process including solvent casting followed by thermal mixing, after achieving the optimized concentration for each filler. The optical characterization of the fresh composites showed an excellent response to selective excitation, with well- defined intraionic lines for TbMOF @ 542 nm ( 5D4/7F5) and for EuMOF @ 615 nm (5D0/7F2). PLA/Eu, TbMOF composites were also explored to create an additional level of encryption by tuning the emitted color with the appropriate excitation stimuli. Hence, these new luminescent composite materials can be used as traceable optical tags for a wide variety of polymeric products, capable to respond to a very specific excitation wavelength and act as a level three luminescent security marker, whose decoding demands the assessment of more than one factor, with near-impossible replication. Additionally, this technology has a high potential for scalability since the applied processing techniques used for the production of the optically active QR code are commonly employed in the polymer industry. Never- theless, the analysis of the aged effects clearly indicates the need for a definition of new strategies to enhance the efficiency of the sensitization process of the Ln 3þ intraionic emission.pt_PT
dc.language.isoengpt_PT
dc.publisherElsevierpt_PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00481%2F2020/PTpt_PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00481%2F2020/PTpt_PT
dc.relationLA/P/0037/2020pt_PT
dc.relationCENTRO-01-0145-FEDER-022083pt_PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50025%2F2020/PTpt_PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50025%2F2020/PTpt_PT
dc.relationLA/P/0037/2020pt_PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PTpt_PT
dc.rightsembargoedAccesspt_PT
dc.subjectPolylactic acidpt_PT
dc.subjectLanthanide metal-organic frameworkpt_PT
dc.subjectHybridspt_PT
dc.subjectLuminescent polymeric compositespt_PT
dc.subject3D printingpt_PT
dc.subjectAnti-counterfeitingpt_PT
dc.titleBoosting the optical properties of polylactic acid/ lanthanide-based metal-organic framework compositespt_PT
dc.typearticlept_PT
dc.description.versionpublishedpt_PT
dc.peerreviewedyespt_PT
degois.publication.titleMaterials Today Chemistrypt_PT
degois.publication.volume29pt_PT
dc.identifier.doi10.1016/j.mtchem.2023.101436pt_PT
dc.identifier.essn2468-5194pt_PT
dc.identifier.articlenumber101436pt_PT
Appears in Collections:TEMA - Artigos
DEM - Artigos
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