Please use this identifier to cite or link to this item:
http://hdl.handle.net/10773/32188
Title: | The orthorhombic-tetragonal morphotropic phase boundary in high-pressure synthesized BiMg0.5Ti0.5O3–BiZn0.5Ti0.5O3 perovskite solid solutions |
Author: | Salak, Andrei N. Shvartsman, Vladimir V. Cardoso, João Pedro Pushkarev, Anatoli V. Radyush, Yury V. Olekhnovich, Nikolai M. Khalyavin, Dmitry D. Vieira, Joaquim M. Čižmár, Erik Feher, Alexander |
Keywords: | High-pressure synthesis Lead-free Oxygen octahedral tilting Piezoresponse force microscopy |
Issue Date: | Feb-2022 |
Publisher: | Elsevier |
Abstract: | (1–x)BiMg0.5Ti0.5O3− xBiZn0.5Ti0.5O3 [(1− x)BMT–xBZT] ceramics of perovskite solid solutions, in which BMT and BZT are lead-free structural analogs of PbZrO3 and PbTiO3, respectively, have been synthesized under high pressure. It was found that the as-prepared compositions with a relative BZT content of <75 mol% are orthorhombic (space group Pnnm), while those with a BZT content above this value are tetragonal (P4mm). In the solution with x = 0.75, both phases coexist forming a morphotropic phase boundary (MPB). The compositional dependence of the normalized unit cell volume exhibits a ~5% jump at x = 0.75. At the same time, the microstructure of the obtained (1–x)BMT− xBZT ceramics shows no particular variation with the chemical composition over MPB. Piezoresponse force microscopy measurements indicate the ferroelectric state of the studied materials and allowed one to estimate their intrinsic piezoelectric coefficients. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/32188 |
DOI: | 10.1016/j.jpcs.2021.110392 |
ISSN: | 0022-3697 |
Appears in Collections: | CICECO - Artigos DEP - Artigos |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
jpcs161_110392.pdf | 3.01 MB | Adobe PDF |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.