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http://hdl.handle.net/10773/25401
Title: | A comparative study of co-precipitation and sol-gel synthetic approaches to fabricate cerium-substituted Mg Al layered double hydroxides with luminescence properties |
Author: | Smalenskaite, A. Vieira, D.E.L. Salak, A.N. Ferreira, M. G. S. Katelnikovas, A. Kareiva, A. |
Keywords: | Layered double hydroxides Co-precipitation Sol-gel processing Cerium substitution effects Luminescent properties |
Issue Date: | 1-Jul-2017 |
Publisher: | Elsevier |
Abstract: | Mg/Al/Ce layered double hydroxides (LDHs) intercalated with carbonate and hydroxide anions were synthesized using co-precipitation and sol-gel method. The obtained materials were characterized by thermogravimetric (TG) analysis, X-ray diffraction (XRD) analysis, fluorescence spectroscopy (FLS) and scanning electron microscopy (SEM). The chemical composition, microstructure and luminescent properties of these LDHs were investigated and discussed. The Ce3 + substitution effects were investigated in the Mg3Al1 − xCex LDHs by changing the Ce3 + concentration in the metal cation layers from 0.05 to 10 mol%. It was demonstrated, that luminescence properties of cerium-substituted LDHs depend on the morphological features of the host lattice. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/25401 |
DOI: | 10.1016/j.clay.2017.03.036 |
ISSN: | 0169-1317 |
Appears in Collections: | CICECO - Artigos |
Files in This Item:
File | Description | Size | Format | |
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Smalenskaite_ACS-2017.pdf | 1.89 MB | Adobe PDF | View/Open |
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