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http://hdl.handle.net/10773/23884
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DC Field | Value | Language |
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dc.contributor.author | Abdelhameed, Reda M. | pt_PT |
dc.contributor.author | Emam, Hossam E. | pt_PT |
dc.contributor.author | Rocha, João | pt_PT |
dc.contributor.author | Silva, Artur M. S. | pt_PT |
dc.date.accessioned | 2018-07-27T08:50:22Z | - |
dc.date.available | 2018-07-27T08:50:22Z | - |
dc.date.issued | 2017-05 | - |
dc.identifier.issn | 0378-3820 | pt_PT |
dc.identifier.uri | http://hdl.handle.net/10773/23884 | - |
dc.description.abstract | Viscose and wool fabrics were modified by the insertion of the metal organic framework copper(II) benzene-1,3,5-tricarboxylate (Cu-BTC MOF) through two different techniques, ex situ (ex-Cu-BTC@fabric) and in situ (Cu-BTC@fabric), and the obtained new materials used to remove phenol from petroleum fractions. The copper and MOF contents were, respectively, 32.3-34.5 mg g(-1) and 102.1-110.0 mg g(-1) for in situ, and 15.6-17.3 mg g-1 and 50.0-55.2 mg g(-1), for ex situ modified fabrics. The efficiency of phenol removal from n-octane was followed the order of fabric < ex-Cu-BTC@fabric < Cu-BTC@fabric and viscose fabric exhibited much higher affinity. The highest phenol removal percentage (90%) was attained after 12 h contact time. The maximum adsorption capacity was 333 mg g(-1) for Cu-BTC@viscose and 306 mg g(-1) after 6 successive recovering cycles. The adsorption was pseudo-second order and well fitted to the Langmuir isotherm. The adsorption mechanism may occur via the (i) physical deposition into the Cu-BTC pores, (ii) hydrogen bonding between the phenol by droxy groups and those of cellulose, and (iii) Cu(II) phenol chelation. The results showed that the insertion of Cu-BTC MOF into natural fabrics is a promising way to effectively remove phenols from fuel. | pt_PT |
dc.language.iso | eng | pt_PT |
dc.publisher | Elsevier | pt_PT |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147332/PT | pt_PT |
dc.rights | restrictedAccess | pt_PT |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | pt_PT |
dc.subject | Natural fabrics | pt_PT |
dc.subject | MOF | pt_PT |
dc.subject | Phenol | pt_PT |
dc.subject | Fuel purification | pt_PT |
dc.subject | Adsorption | pt_PT |
dc.subject | Reusability | pt_PT |
dc.title | Cu-BTC metal-organic framework natural fabric composites for fuel purification | pt_PT |
dc.type | article | pt_PT |
dc.description.version | published | pt_PT |
dc.peerreviewed | yes | pt_PT |
degois.publication.firstPage | 306 | pt_PT |
degois.publication.lastPage | 312 | pt_PT |
degois.publication.title | Fuel Processing Technology | pt_PT |
degois.publication.volume | 159 | pt_PT |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0378382016313029?via%3Dihub | pt_PT |
dc.identifier.doi | 10.1016/j.fuproc.2017.02.001 | pt_PT |
Appears in Collections: | CICECO - Artigos DQ - Artigos QOPNA - Artigos |
Files in This Item:
File | Description | Size | Format | |
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documento.pdf | 1.24 MB | Adobe PDF |
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