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http://hdl.handle.net/10773/20889| Title: | Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties |
| Author: | Vilela, Sergio M. F. Firmino, Ana D. G. Mendes, Ricardo F. Fernandes, Jose A. Ananias, Duarte Valente, Anabela A. Ott, Holger Carlos, Luis D. Rocha, Joao Tome, Joao P. C. Almeida Paz, Filipe A. |
| Keywords: | METAL-ORGANIC FRAMEWORKS FUNCTIONALITY LUMINESCENCE COMPLEXES DESIGN TEMPERATURE SEPARATION NUMBER IONS SIZE |
| Issue Date: | 2013 |
| Publisher: | ROYAL SOC CHEMISTRY |
| Abstract: | A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H(4)bmt)(H(5)bmt)(H2O)(2)]center dot 3H(2)O coordination polymers is presented. The La3+-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu3+- and Tb3+-doped materials are very effective UV-to-visible light converters. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20889 |
| DOI: | 10.1039/c3cc42632g |
| ISSN: | 1359-7345 |
| Publisher Version: | 10.1039/c3cc42632g |
| Appears in Collections: | CICECO - Artigos |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties_10.1039c3cc42632g.pdf | 1.01 MB | Adobe PDF |  |
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