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http://hdl.handle.net/10773/20803| Title: | Synthesis, characterizations and structure of orthometallated Pt(II) and Pt(IV) complexes: Oxidative addition to C,N,N,O coordinated Pt(II) complexes |
| Author: | Pattanayak, Poulami Parua, Sankar Prasad Patra, Debprasad Pratihar, Jahar Lal Brandao, Paula Felix, Vitor Chattopadhyay, Surajit |
| Keywords: | C-H ACTIVATION HETEROGENEOUS CATALYSIS PLATINUM(II) COMPLEXES VISIBLE-LIGHT PALLADIUM REACTIVITY LIGAND NANOPARTICLES REDUCTION PALLADACYCLES |
| Issue Date: | 2014 |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| Abstract: | Reactions of 2-(arylazo)-1-N-salicylidene phenylamine, H2L, 1, [H represents the dissociable protons upon complexation], with K2PtCl4 afforded orthometallated complexes of composition [Pt(L)], 2 where the Pt(II) is coordinated by the tetradentate (C,N,N,O) ligand, L2-. Reaction of the precursor complex [Pt(L)] with I-2 afforded octahedral complexes of composition [PtI2(L)], 3. All the complexes were characterized unequivocally. X-ray crystal structure of [Pt(L-1)] and [Pt I-2(L-1)] have been determined. (C) 2014 Published by Elsevier Ltd. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/20803 |
| DOI: | 10.1016/j.poly.2013.12.014 |
| ISSN: | 0277-5387 |
| Publisher Version: | 10.1016/j.poly.2013.12.014 |
| Appears in Collections: | CICECO - Artigos |
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| Synthesis characterizations and structure of orthometallated Pt(II) and Pt(IV) complexes Oxidative addition to CNNO coordinated Pt(II) complexes_10.1016j.poly.2013.12.014.pdf | 464.38 kB | Adobe PDF |  |
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