Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/20565
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dc.contributor.authorKaushal, A.pt
dc.contributor.authorOlhero, S. M.pt
dc.contributor.authorSingh, Budhendrapt
dc.contributor.authorFagg, Duncan P.pt
dc.contributor.authorBdikin, Igorpt
dc.contributor.authorFerreira, J. M. F.pt
dc.date.accessioned2017-12-07T19:51:39Z-
dc.date.issued2014pt
dc.identifier.issn0272-8842pt
dc.identifier.urihttp://hdl.handle.net/10773/20565-
dc.description.abstractThis work aims to contribute new data on the dielectric relaxation behavior of the lead-free piezoelectric 0.5Ba(Zr0.2Ti0.8)O-3-0.5(Ba0.7Ca0.3) TiO3 (BZT-BCT) material processed in aqueous media. To obtain a BZT-BCT ceramic with high density, an aqueous suspension of BZT-BCT material was successfully transferred to spherical granules via freeze granulation, followed by sintering of a consolidated high green dens compact at 1350 degrees C for 4 h. The dielectric relaxation behavior in the temperature range 300-600 degrees C over the frequency range of 0.1 Hz-1 MHz has been carried out to display the characteristic of dielectric relaxation behavior of the BZT-BCT ceramic. Two distinct temperature dependent peaks at characteristic frequencies were observed, which shift towards the high frequency end with increasing temperature, depicting a thermally activated relaxation phenomena in the BZT-BCT ceramic. The dependences of dielectric parameters by fitting data with Cole-Cole equations (Nyquist plot) on temperature have been discussed in detail. Relaxation time was found to decrease with increasing temperature and to obey the Arrhenius relationship. The values of calculated resistances were found to be of same order for bulk (R-b) and grain boundary (R-gb) contributions, whereas capacitance values calculated for bulk (C-b) were found to be 2 orders more than that of capacitance values calculated for grain boundaries (C-gb). (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.pt
dc.language.isoengpt
dc.publisherELSEVIER SCI LTDpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F77598%2F2011/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F87486%2F2012/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F76184%2F2011/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/105424/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/COMPETE/132936/PTpt
dc.rightsrestrictedAccesspor
dc.subjectTEMPERATURE-COEFFICIENTpt
dc.subjectDIELECTRIC-PROPERTIESpt
dc.subjectMODULUS SPECTROSCOPYpt
dc.subjectPHASE-TRANSITIONpt
dc.subjectCAPACITORSpt
dc.subjectCONDUCTIONpt
dc.titleImpedance analysis of 0.5Ba(Zr0.2Ti0.8)O-3-0.5(Ba0.7Ca0.3)TiO3 ceramics consolidated from micro-granulespt
dc.typearticlept
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage10593pt
degois.publication.issue7pt
degois.publication.lastPage10600pt
degois.publication.titleCERAMICS INTERNATIONALpt
degois.publication.volume40pt
dc.date.embargo10000-01-01-
dc.relation.publisherversion10.1016/j.ceramint.2014.03.038pt
dc.identifier.doi10.1016/j.ceramint.2014.03.038pt
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