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http://hdl.handle.net/10773/20469
Title: | Synthesis and characterization of pyrimidyl- and pyrazinylselenium compounds: X-ray structure of 2,5-bis(methylselenenyl)pyrazine |
Author: | Dhau, Jaspreet S. Singh, Avtar Singh, Amritpal Dhir, Rupy Brandao, Paula Felix, Vitor |
Keywords: | BIOLOGICAL-ACTIVITY CRYSTAL-STRUCTURE PYRIDYLSELENIUM COMPOUNDS ORGANOSELENIUM COMPOUNDS ANTIOXIDANT ACTIVITY COMPLEXES PYRIDYL SE TE NANOCRYSTALS |
Issue Date: | 2014 |
Publisher: | ELSEVIER SCIENCE SA |
Abstract: | A methodology for the lithiation of pyrimidine (1a) was developed and used for the synthesis of pyrimidylselenium compounds. The procedure involved prior complexation of 1a with 2.2 equiv. of BF3 center dot Et2O followed by a reaction with LDA or LTMP. The pyrazinylselenium derivatives were synthesized from the direct lithiation of pyrazine (1b) as the BF3-directed lithiation failed to give the desired products. All the synthesized compounds were characterized by elemental analysis, NMR (H-1 and C-13) and Mass spectroscopy. In addition, 2,5-bis(methylselenenyl)pyrazine (9b) was characterized by single crystal X-ray crystallography. (C) 2014 Elsevier B.V. All rights reserved. |
Peer review: | yes |
URI: | http://hdl.handle.net/10773/20469 |
DOI: | 10.1016/j.ica.2014.06.025 |
ISSN: | 0020-1693 |
Publisher Version: | 10.1016/j.ica.2014.06.025 |
Appears in Collections: | CICECO - Artigos |
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File | Description | Size | Format | |
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Synthesis and characterization of pyrimidyl- and pyrazinylselenium compounds X-ray structure of 25-bis(methylselenenyl)pyrazine_10.1016j.ica.2014.06.025.pdf | 267.74 kB | Adobe PDF |
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