Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/20273
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dc.contributor.authorBruno, Sofia M.pt
dc.contributor.authorGomes, Ana C.pt
dc.contributor.authorOliveira, Tania S. M.pt
dc.contributor.authorAntunes, Margarida M.pt
dc.contributor.authorLopes, Andre D.pt
dc.contributor.authorValente, Anabela A.pt
dc.contributor.authorGoncalves, Isabel S.pt
dc.contributor.authorPillinger, Martynpt
dc.date.accessioned2017-12-07T19:41:20Z-
dc.date.issued2016pt
dc.identifier.issn1477-0520pt
dc.identifier.urihttp://hdl.handle.net/10773/20273-
dc.description.abstractMetal-free cucurbit[7]uril (CB7) solid-state assemblies promote acid-catalysed alcoholysis of aliphatic and aromatic epoxides under mild conditions to give beta-alkoxy alcohols, which are important intermediates for the synthesis of a vast range of compounds such as bioactive pharmaceuticals. The catalytic process is heterogeneous and the catalyst can be reused in consecutive runs without any reactivation treatment. The acid species responsible for the catalytic activity of CB7 may be entrapped hydronium ions.pt
dc.language.isoengpt
dc.publisherROYAL SOC CHEMISTRYpt
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/147332/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/5876-PPCDTI/127348/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F46473%2F2008/PTpt
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F89068%2F2012/PTpt
dc.rightsrestrictedAccesspor
dc.subjectBETA-ALKOXY ALCOHOLSpt
dc.subjectSUPRAMOLECULAR CATALYSISpt
dc.subjectEFFICIENT CATALYSTpt
dc.subjectACID CATALYSTpt
dc.subjectOXIDATIONpt
dc.titleCatalytic alcoholysis of epoxides using metal-free cucurbituril-based solidspt
dc.typearticlept
dc.peerreviewedyespt
ua.distributioninternationalpt
degois.publication.firstPage3873pt
degois.publication.issue16pt
degois.publication.lastPage3877pt
degois.publication.titleORGANIC & BIOMOLECULAR CHEMISTRYpt
degois.publication.volume14pt
dc.date.embargo10000-01-01-
dc.relation.publisherversion10.1039/c6ob00512hpt
dc.identifier.doi10.1039/c6ob00512hpt
Appears in Collections:CICECO - Artigos

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