Please use this identifier to cite or link to this item: http://hdl.handle.net/10773/20110
Title: A layered erbium phosphonate in pseudo-D-5h symmetry exhibiting field-tunable magnetic relaxation and optical correlation
Author: Ren, Min
Bao, Song-Song
Ferreira, Rute A. S.
Zheng, Li-Min
Carlos, Luis D.
Keywords: SINGLE-MOLECULE MAGNET
ION MAGNET
ANISOTROPY
COMPLEXES
DYSPROSIUM(III)
BEHAVIOR
HYSTERESIS
DYNAMICS
EXCHANGE
BLOCKING
Issue Date: 2014
Publisher: ROYAL SOC CHEMISTRY
Abstract: A layered erbium(III) phosphonate compound, [Er(notpH(4))(H2O)]ClO4 center dot 3H(2)O (1), in which the Er-III ion has a pseudo-D-5h symmetry exhibits field tunable multiple magnetic relaxation. The near-IR emission spectrum of 1, excited at 1064 nm (Nd:YAG laser), provides a direct probe of the crystal field splitting correlated to the magnetic data.
Peer review: yes
URI: http://hdl.handle.net/10773/20110
DOI: 10.1039/c4cc02085e
ISSN: 1359-7345
Publisher Version: 10.1039/c4cc02085e
Appears in Collections:CICECO - Artigos



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