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Title: Synthesis and physical properties of Ca- and Ta-modified (K,Na)NbO3 lead-free piezoelectric ceramics
Author: Coondoo, Indrani
Panwar, Neeraj
Rai, Radheshyam
Amorin, Harvey
Kholkin, Andrei L.
Keywords: THIN-FILMS
Issue Date: 2013
Abstract: Polycrystalline samples of lead-free Ca and Ta co-substituted potassium sodium niobate (K0.5Na0.5NbO3, KNN) ceramics have been prepared by solid state reaction technique. X-ray diffraction showed formation of a single-phase perovskite structure with orthorhombic symmetry. Substitution inhibits the grain growth, improves densification and decreases the ferro-paraelectric phase transition temperature. Temperature dependent dielectric permittivity studies demonstrate significant decrease in peak-permittivity values in the substituted samples. Bulk longitudinal piezoelectric coefficient is significantly enhanced, up to approximate to 155 pC/N for (K0.48Na0.48Ca0.02)(Nb0.85Ta0.15O3) as compared to 95 pC/N for pristine KNN ceramic. Local piezoelectric properties have been observed by piezoresponse force microscopy (PFM) technique. Distinct piezocontrast was studied in both vertical and in-plane modes of PFM for all samples. The samples exhibit self-polarization effect in the unpoled state and effective local vertical piezoelectric coefficient was the largest in Ca and Ta co-substituted sample whereas the in-plane piezoelectric coefficient was maximum for Ca-substituted KNN sample. These studies are important for using substituted lead free KNN materials in various piezoelectric applications.
Peer review: yes
DOI: 10.1080/01411594.2013.790032
ISSN: 0141-1594
Publisher Version: 10.1080/01411594.2013.790032
Appears in Collections:CICECO - Artigos

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