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http://hdl.handle.net/10773/19667| Title: | A High-Temperature Molecular Ferroelectric Zn/Dy Complex Exhibiting Single-Ion-Magnet Behavior and Lanthanide Luminescence |
| Author: | Long, Jerome Rouquette, Jerome Thibaud, Jean-Marc Ferreira, Rute A. S. Carlos, Luis D. Donnadieu, Bruno Vieru, Veaceslav Chibotaru, Liviu F. Konczewicz, Leszek Haines, Julien Guari, Yannick Larionova, Joulia |
| Keywords: | BIS(IMIDAZOLIUM) L-TARTRATE RELAXATION FIELD ANISOTROPY POLYMERS CRYSTAL DESIGN |
| Issue Date: | 2015 |
| Publisher: | WILEY-V C H VERLAG GMBH |
| Abstract: | Multifunctional molecular ferroelectrics are exciting materials synthesized using molecular chemistry concepts, which may combine a spontaneous electrical polarization, switched upon applying an electric field, with another physical property. A high-temperature ferroelectric material is presented that is based on a chiral Zn2+/Dy3+ complex exhibiting Dy3+ luminescence, optical activity, and magnetism. We investigate the correlations between the electric polarization and the crystal structure as well as between the low-temperature magnetic slow relaxation and the optical properties. |
| Peer review: | yes |
| URI: | http://hdl.handle.net/10773/19667 |
| DOI: | 10.1002/anie.201410523 |
| ISSN: | 1433-7851 |
| Publisher Version: | 10.1002/anie.201410523 |
| Appears in Collections: | CICECO - Artigos |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| A High-Temperature Molecular Ferroelectric ZnDy Complex Exhibiting Single-Ion-Magnet Behavior and Lanthanide Luminescence_10.1002anie.201410523.pdf | 881.98 kB | Adobe PDF |  |
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